Development of singlet oxygen-responsive phosphorescent ruthenium(II) complexes.
نویسندگان
چکیده
By using an anthryl-substituted 2,2'-bipyridine as a singlet oxygen-reactive ligand, a new class of Ru(II)-bipyridine complex derivatives that can specifically respond to singlet oxygen with remarkable phosphorescence enhancements have been successfully developed.
منابع مشابه
Microenvironment-switchable singlet oxygen generation by axially-coordinated hydrophilic ruthenium phthalocyanine dendrimers.
A series of new metallodendrimers built around a ruthenium phthalocyanine core has been prepared. Employing a convergent synthetic strategy, pyridine-containing ligands were prepared and then assembled onto the ruthenium phthalocyanine through axial ligand coordination. The growing shell of oligoethylene glycol chains surrounding the lipophilic core allows solubilisation in water. Photophysical...
متن کاملTris(tetramethylphenanthroline)ruthenium(II): a chiral probe that cleaves A-DNA conformations.
lambda-Tris(3,4,7,8-tetramethyl-1,10-phenanthroline)ruthenium(II) [lambda-Ru(TMP)2+3] was found to be a distinctive molecular tool to examine the local variations in conformation along the strand. The metal complex binds cooperatively to A-form helices of various base sequences under conditions where little or no binding was found to analogous B-form DNAs. Photoactivated DNA cleavage may be cou...
متن کاملCombination of visible-light responsive heterogeneous and homogeneous photocatalysts for water oxidation.
Bismuth vanadate (BiVO(4)), which is a visible-light responsive heterogeneous photocatalyst, was combined with homogeneous ruthenium complexes to increase the overall photocatalytic reactivity for water oxidation with a one-electron oxidant, [Co(III)(NH(3))(5)Cl](2+). Photoinduced electron transfer from the excited state of ruthenium(II) complexes to [Co(III)(NH(3))(5)Cl](2+) affords ruthenium(...
متن کاملA quenched binuclear ruthenium(II) dimer activated by another photosensitizer.
A binuclear ruthenium(II) dimer (BiRD) bridged by an alkene linker was synthesized that was labile to reactive oxygen species generated by another photosensitizer. Compared to the monomeric Ru(II) complex, the BiRD had attenuated fluorescence and singlet oxygen production which could be restored by a longer-wavelength photosensitizer. This two-step amplification strategy demonstrates proof-of-p...
متن کاملHomogeneous luminescence decay time-based assay using energy transfer from nanospheres.
Following a study on the feasibility of resonance energy transfer (RET) from carboxylated nanospheres with an incorporated phosphorescent donor to a cationic polyelectrolyte/acceptor aggregate on their surface, a novel scheme for homogeneous assays is presented that is based on RET from phosphorescent biotinylated nanospheres to fluorescently labeled streptavidin (SA). The phosphorescent nanosp...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 42 40 شماره
صفحات -
تاریخ انتشار 2013